Update:
We struggled on emissions again to get an MOT, but scraped through. Advisory on rear brakes so I have done a bit of fettling.
Rear cylinder was weeping on one side so I ordered a brake shoe set and fixing kit. When I took the rear hubs off, the bearings came apart so I had to replace the rear hubs too. The cylinder arrived but had only one fixing hole in it which was the wrong side so couldn't be bolted in. A replacement had a hole for both sides so went straight in.
I had ordered a full exhaust and cat after last year but hadn't fitted it, and the front wheel bearings needed doing, but I farmed out the work as the exhaust was pretty rusty and my press was out of action. They were renewed when we recommissioned the car but the quality of bearings can be very poor so FAG ones were fitted as advised by our friendly VW friendly specialist.
Got the car back and was advised to get the alignment set up as it was out of line. The mystery of the emissions was also solved as the "Cat" had no internals. Nothing. Just a shell of one!
Got the alignment done (£50) and the car now drives perfectly. If you ever change the struts or hubs get it checked as it has made a huge difference.
Hopefully the MOT next year will have no emissions related malarkey.